Chemical Reviews. Trichloromethyl chloroformate "diphosgene" , ClCOOCCl3: structure and conformational properties in the gaseous and condensed phases. The Journal of Organic Chemistry. Gas electron diffraction study of the vapour over dimethylamine-gallane leading to an improved structure for dimeric dimethylamidogallane, [Me2NGaH2]2: a cautionary tale. Synthesis and structural characterisation of primary amine adducts of gallane, RH2N. Decomposition of monochlorogallane, [H2GaCl]n, and adducts with amine and phosphine bases: formation of cationic gallane derivatives.
GaH3: an unusually strongly bound gallane adduct. Acta Crystallographica.
Section C, Crystal Structure Communications. Crystal structures of tris tert-butyl boron, -aluminum, -gallium, and -indium: Nonplanarity of the AlC3 skeleton and evidence of inter- and intramolecular "agostic" or hyperconjugative interactions Organometallics. Some novel binuclear group 13 metal tin hydrides formed in Ar matrices following the codeposition of the metal vapor with SnH4. Matrix reactivity of Al and Ga atoms M in the presence of silane: generation and characterization of the eta2-coordinated complex M.
Molecular structure of Hf BH4 4 investigated by quantum mechanical calculations and gas-phase electron diffraction.
Polymorphism in the crystal structures of the group 13 trimethyls Organometallics. The length, strength and polarity of metal-carbon bonds: Dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and photoelectron spectroscopy Dalton Transactions. Dalton Transactions. Characterization and photochemistry of the gallium and indium subhydrides Ga2H2 and In2H2. Angewandte Chemie International Ed. Molecular structures of two metal tetrakis tetrahydroborates , Zr BH4 4 and U BH4 4 : equilibrium conformations and barriers to internal rotation of the triply bridging BH4 groups.
Reactions of ground state and electronically excited atoms of main group elements: a matrix perspective. Formation and characterization of the gallium and indium subhydride molecules Ga2H2 and In2H2: a matrix isolation study. Low valent and would-be multiply bonded derivatives of the Group 13 metals Al, Ga and In revealed through matrix isolation Polyhedron. Hydrides of the main-group metals: new variations on an old theme. Structure and conformational properties of diacetyl sulfide in the gaseous and condensed phases explored by gas electron diffraction, single-crystal X-ray diffraction, vibrational spectroscopy, and quantum chemical calculations.
Preparation and properties of gallaborane, GaBH 6 : structure of the gaseous molecule H 2 Ga mu-H 2 BH 2 as determined by vibrational, electron diffraction, and ab initio studies, and structure of the crystalline solid at K as determined by X-ray diffraction.
Reactions of aluminum, gallium, and indium M atoms with phosphine: generation and characterization of the species M. Thermal and photolytic reactions of gallium and indium atoms M and their dimers ma with carbon monoxide in low-temperature matrices: Formation of terminal, bridged, and ionic carbonyl derivatives Journal of Physical Chemistry A. Molecular recognition in the solid state: Topology of experimental and theoretical charge densities for tetrasulfur tetranitride Chemical Communications.
In earlier treatments, however, the distinction between normal compounds of the metals and genuine coordination compounds formed by addition to such compounds has not always been clear, leading to repetition and unnecessary overlap. Organisation will be by ligand type, and for each ligand type the metals will generally be treated in turn, with a further sub-division, as necessary, by oxidation state.
Rather than having separate chapters on the biological, environmental and medical roles of the metals cf.
The last two decades have seen a renaissance of interest in thechemistry of the Main Group elements. In particular, research onthe metals of Group 13 aluminium, gallium, indium and thallium has led to the synthesis and isolation of some novel and unusualcompounds with implications, for examples, in organometallicsynthesis, in new materials development, and in biological,medical, and environmental systems.
The Group 13 Metals Aluminium, Gallium, Indium andTallium aims to cover new facts, developments, and applicationsin the context of more general patterns of physical and chemicalbehaviour, with an eye to both the homogeneity and heterogeneitydisplayed by the elements.
Problem URL. Enter your email address below and we will send you your username. Metalloid Clusters and their Relationship to. Surface Complexation Modeling Gibbsite. The nearly exhaustive collection of literature references reflects the state of the art up to , or even Chapters cover:.
Particular attention is paid to the maingrowth areas, including the chemistry of lower formal oxidationstates, cluster chemistry, solid oxides and hydroxides, methods offormation of III-V and related compounds, the biologicalsignificance of Group 13 metal compounds, and the growingimportance of the metals and their compounds in the mediation oforganic reactions. The Group 13 Metals Aluminium, Gallium, Indium andThallium provides a detailed, wide-ranging, and up-to-datereview of the chemistry of this important group of metals.
Inorganic Chemistry Catherine E. Advances in Physical Organic Chemistry.
The Periodic Table Eric R. We appreciate your feedback. Progress in Inorganic Chemistry. It willfind a place on the bookshelves of researchers and otherexperienced scientists as well as students in inorganic, organic,organometallic, and material chemistry. Would you like to tell us about a lower price? If you are a seller for this product, would you like to suggest updates through seller support? Learn more about Amazon Prime.
The last two decades have seen a renaissance in interest in thechemistry of the main group elements. In particular research on themetals of group 13 aluminium, gallium, indium and thallium hasled to the synthesis and isolation of some very novel and unusualmolecules, with implications for organometallic synthesis, newmaterials development, and with biological, medical and,environmental relevance.
Read more Read less. Prime Book Box for Kids. Review "All the chapters in this book are written by leading experts inthe corresponding research areas and offer an excellent overview ofrecent research.
General features of the Group 13 elements. Aluminium and gallium clusters: Simple and mixed metal oxides and hydroxides: Coordination and solution chemistry of the metals: Wiley; 1 edition April 11, Language: Be the first to review this item Amazon Best Sellers Rank: Related Video Shorts 0 Upload your video. Try the Kindle edition and experience these great reading features: Customer reviews There are no customer reviews yet. Share your thoughts with other customers.
The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities. Editor(s). Simon Aldridge; Anthony J. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) Gallium, Indium and Thallium: Chemical Patterns and Peculiarities.